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Potasium 3-sulphopropyl methacrylate

Also known as potassium 3-(2-methylprop-2-enoyloxy)propane-1-sulfonate, 3-Sulfopropyl methacrylate potassium salt, Potassium 3-sulphopropyl methacrylate, 1H3W483Z72

Potasium 3-sulphopropyl methacrylate is an ionic methacrylate compound with the molecular formula C7H11KO5S and molecular weight 246.32. Its structure combines a polymerisable methacrylate group with a 3-sulfopropyl substituent and potassium counterion, supporting research into sulfonated polymers, water-compatible materials and functional copolymers.

Specialty Monomers Sulfonated Methacrylate Monomers

Product identity

CAS number
31098-21-2
Molecular formula
C7H11KO5S
Molecular weight
246.32 g/mol
Category
Specialty Monomers
Subcategory
Sulfonated Methacrylate Monomers
Common aliases
potassium 3-(2-methylprop-2-enoyloxy)propane-1-sulfonate, 3-Sulfopropyl methacrylate potassium salt, Potassium 3-sulphopropyl methacrylate

Product overview

What is Potasium 3-sulphopropyl methacrylate?

Potasium 3-sulphopropyl methacrylate is a specialty, ion-containing methacrylate monomer identified by CAS number 31098-21-2. Its systematic name is potassium 3-(2-methylprop-2-enoyloxy)propane-1-sulfonate, and it is also known as 3-sulfopropyl methacrylate potassium salt. The molecular formula is C7H11KO5S, with a stated molecular weight of 246.32. The potassium sulfonate group and methacrylate functionality define its chemical identity.

The molecule combines a polymerisable methacrylate double bond with a strongly polar sulfonate functionality associated with potassium. This architecture can contribute ionic character, water affinity and compatibility with polar formulation environments, while the unsaturated ester group permits participation in free-radical polymerisation. Actual solubility, stability, reactivity and handling behaviour depend on concentration, formulation, temperature, impurities and the specific processing conditions used.

In established materials chemistry, sulfonated methacrylate monomers are considered when polymer designers seek charged or hydrophilic functionality within copolymers, networks or surface-oriented materials. This compound may therefore be evaluated for specialty polymer synthesis, functional coatings, ion-containing materials and laboratory research. Such uses describe potential formulation roles; suitability for a particular product, process or end market requires technical assessment of the intended grade and conditions.

Selection should begin with the required ionic functionality, comonomer system, solvent environment and polymerisation method. Buyers and formulators should also consider water sensitivity, compatibility with initiators and other ingredients, storage controls, analytical requirements and the effect of potassium counterions on the finished material. A representative sample and process-specific testing are prudent before scale-up, because performance cannot be inferred from chemical identity alone. For commercial selection, the compound name should be considered separately from the specification and supplied form required for the intended process.

Technical profile

Product properties

Review the product identity and general physical profile before specifying the grade required for your operation.

IUPAC name
potassium 3-(2-methylprop-2-enoyloxy)propane-1-sulfonate
Category
Specialty Monomers
Subcategory
Sulfonated Methacrylate Monomers
Molecular formula
C7H11KO5S
Molecular weight
246.32 g/mol

Uses and markets

Applications and industries

The correct product specification depends on the intended process, grade requirements and operating conditions.

Detailed product information

Detailed Potasium 3-sulphopropyl methacrylate product information

Chemical Identity and Functional Architecture

Potasium 3-sulphopropyl methacrylate is a potassium salt of a sulfonated methacrylate monomer. The molecule contains an ester-linked methacrylate group for polymerisation and a terminal sulfonate group that gives it pronounced ionic character. This combination makes it relevant to formulators designing polymers that incorporate both carbon–carbon chain growth and polar, charge-bearing functionality.

The compound is listed under CAS number 31098-21-2 and has the molecular formula C7H11KO5S. Its molecular weight is 246.32. Alternative names include potassium 3-(2-methylprop-2-enoyloxy)propane-1-sulfonate and 3-sulfopropyl methacrylate potassium salt. These identity details help distinguish it from non-sulfonated methacrylates and from other potassium-containing specialty monomers. Performance remains formulation-specific.

Polymerisation and Formulation Considerations

For Potasium 3-sulphopropyl methacrylate, the methacrylate double bond can participate in suitable free-radical polymerisation schemes, including copolymerisation with compatible monomers. The sulfonate group remains an important source of polarity and ionic behaviour within the resulting material. Polymerisation rate, conversion, molecular architecture and final properties depend on initiator selection, solvent, temperature, concentration, atmosphere and comonomer composition.

Because the compound is ionic, its behaviour may differ substantially from that of neutral methacrylate monomers. Water content, counterion effects, pH, ionic strength and phase compatibility can influence dissolution, mixing and polymer growth. Small-scale compatibility studies, analytical monitoring and controlled process development are recommended before applying it in a production formulation or a crosslinked material.

Potential Materials and Research Roles

For Potasium 3-sulphopropyl methacrylate, specialty polymer researchers may investigate this monomer when a formulation requires hydrophilic or charged segments, interfacial functionality or altered interaction with aqueous environments. Possible development areas include functional copolymers, ionic networks, coatings research and surface-oriented materials. These are potential roles rather than universal indications, and the final application depends on the complete polymer composition and manufacturing route.

Its structure can support comparative studies against other sulfonated or polar monomers. Researchers may examine how incorporation affects water interaction, conductivity-related behaviour, adhesion, swelling, dispersion or compatibility. Results should be interpreted for the actual polymer architecture, since a monomer’s functionality does not by itself predict the performance of a finished film, resin, coating or composite.

Selection, Testing and Process Fit

For Potasium 3-sulphopropyl methacrylate, a sensible selection review considers the desired sulfonate content, target molecular architecture, comonomers, reaction medium and downstream purification strategy. It is also useful to establish how the material behaves during weighing, dissolution, charging and reaction under the intended conditions. Technical evaluation should include relevant analytical methods and checks for compatibility with the complete formulation.

Process teams should assess storage and handling requirements through the applicable product documentation and local workplace procedures. They should also determine whether potassium ions influence the intended application, especially where conductivity, water interaction, ion exchange or residual salts matter. Pilot work can reveal issues involving phase separation, viscosity, polymerisation control or purification that are not apparent from formula and nomenclature alone.

Frequently asked questions

Questions about Potasium 3-sulphopropyl methacrylate

What role does the sulfonate group play in this monomer?

The sulfonate group is the principal ionic and strongly polar feature of the molecule. In a polymer, it can increase interaction with water or other polar environments and may influence swelling, dispersion, interfacial behaviour, conductivity-related characteristics and compatibility with charged species. The potassium counterion is part of the supplied salt form and can also affect solution behaviour and final-material properties. The actual outcome depends on how much monomer is incorporated, the neighbouring comonomers, the polymer architecture and the surrounding medium. Therefore, the sulfonate group should be viewed as a design function, not as a guarantee of any particular finished-product performance.

Can Potasium 3-sulphopropyl methacrylate be copolymerised?

Its methacrylate double bond provides a conventional site for investigating free-radical copolymerisation with compatible vinyl or methacrylate comonomers. Whether a particular pairing works well depends on relative reactivity, solvent compatibility, ionic strength, concentration, initiator system, temperature and the desired molecular architecture. Ionic monomers can behave differently from neutral monomers, including showing altered mixing or composition drift during reaction. Development work should therefore begin with controlled laboratory experiments and suitable analytical monitoring. A successful reaction in one solvent or comonomer system should not be assumed to transfer directly to another process without additional evaluation.

What types of materials research may use this compound?

Researchers may consider this monomer for functional copolymers, hydrophilic or ion-containing networks, surface-modifying materials and specialty coatings research. It can be useful when a polymer design requires a methacrylate polymerisation handle together with sulfonate functionality. Potential investigation areas include aqueous interaction, swelling, dispersion, interfacial response and charge-related behaviour. These possibilities do not establish suitability for a specific commercial application. The final performance depends on incorporation level, polymer structure, crosslink density, other ingredients, processing conditions and the environment in which the finished material operates. Comparative testing against alternative ionic monomers can clarify its practical value.

How can ionic character affect formulation behaviour?

Ionic character can influence dissolution, mixing, phase behaviour, viscosity, water uptake and interactions with other charged or polar ingredients. In some systems, the potassium salt form may improve compatibility with aqueous or polar media; in others, it may create challenges involving salt sensitivity, limited compatibility or nonuniform distribution. The result depends strongly on solvent composition, pH, ionic strength, concentration and temperature. Formulators should evaluate the complete ingredient set rather than relying on the monomer structure alone. Observing appearance, homogeneity, viscosity and stability during representative bench trials can provide useful early information before more extensive polymerisation or application testing.

What factors should be reviewed before polymerisation trials?

Important factors include the selected initiator, reaction temperature, monomer concentration, solvent or solvent mixture, atmosphere, agitation and comonomer ratio. The team should also consider whether the ionic monomer remains uniformly distributed throughout the reaction and whether heat or viscosity changes could affect control. Analytical plans may include conversion monitoring and characterization of the resulting polymer’s composition and molecular properties. Because polymerisation is condition-dependent, trial work should use documented procedures, suitable engineering controls and process-specific risk assessment. Results from a small experiment should be reviewed before increasing scale, changing solvent, or introducing the material into a different formulation.

How does this compound differ from methyl methacrylate?

Methyl methacrylate is a neutral methacrylate ester, whereas Potasium 3-sulphopropyl methacrylate contains an additional sulfonate-bearing propyl group and is supplied as a potassium salt. Both structures include methacrylate functionality capable of polymerisation under suitable conditions, but their polarity, ionic character, solubility behaviour and interactions with formulation components can differ substantially. Consequently, replacing one with the other is not a simple one-for-one substitution. The choice should reflect the intended polymer architecture and property targets, followed by compatibility and performance testing under the actual reaction and application conditions. The final decision should be based on the supplied specification, intended process and applicable requirements rather than the chemical name alone.

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