Also known as magnesium dihydroxide, Milk of magnesia, Magnesium hydrate, Magnesium hydroxide (Mg(OH)2)
Magnesium Hydroxide (magnesium dihydroxide), CAS 1309-42-8, is an inorganic base with the formula H2MgO2. Miilex Chemicals presents it for technically evaluated use in plastics, water treatment, pharmaceutical and related chemical applications.
Inorganic baseMagnesium hydroxide base
Product identity
CAS number
1309-42-8
Molecular formula
H2MgO2
Molecular weight
58.320 g/mol
Category
Inorganic base
Subcategory
Magnesium hydroxide base
Common aliases
magnesium dihydroxide, Milk of magnesia, Magnesium hydrate
Product overview
What is Magnesium Hydroxide?
Magnesium Hydroxide is an inorganic magnesium compound also known as magnesium dihydroxide, magnesium hydrate and Mg(OH)2. Its CAS number is 1309-42-8, molecular formula is H2MgO2, and molecular weight is 58.320. The material consists of magnesium ions associated with hydroxide ions, giving it the characteristic composition of a metal hydroxide. It is commonly encountered as a solid powder or as a dispersed suspension.
Magnesium Hydroxide is a sparingly soluble inorganic base rather than a strongly soluble alkali. In contact with acidic materials, its hydroxide component can neutralize acidity while magnesium enters the resulting salt system. Its limited solubility can support controlled reaction behaviour, although dispersion, particle characteristics, temperature and the surrounding formulation influence practical performance. Heating can promote decomposition to magnesium oxide and water, subject to the conditions used.
Established technical contexts for Magnesium Hydroxide include acid neutralization, selected wastewater-treatment processes, flame-retardant systems and pharmaceutical formulations such as antacid products. It may also appear in personal-care and materials development work where an alkaline magnesium compound is being evaluated. These uses describe recognized application areas, not universal suitability; the appropriate form, purity, particle profile and regulatory status depend on the finished product and jurisdiction.
Selecting Magnesium Hydroxide requires consideration of the intended reaction, required dispersion, contact medium, particle-size behaviour and compatibility with surrounding ingredients. A formulation may need a powder that processes differently from a prepared suspension, while a polymer compound may require careful assessment of loading, moisture and thermal behaviour. Buyers should compare the chemical's documented characteristics with their own process, end-use requirements and applicable local rules before adoption.
Technical profile
Product properties
Review the product identity and general physical profile before specifying the grade required for your operation.
IUPAC name
magnesium dihydroxide
Category
Inorganic base
Subcategory
Magnesium hydroxide base
Molecular formula
H2MgO2
Molecular weight
58.320 g/mol
Uses and markets
Applications and industries
The correct product specification depends on the intended process, grade requirements and operating conditions.
Magnesium Hydroxide chemistry and neutralization behaviour
Magnesium Hydroxide, Mg(OH)2, is a sparingly soluble inorganic base whose hydroxide ions can react with acids. This behaviour makes it useful where gradual neutralization is preferred over the immediate dissolution associated with highly soluble alkaline materials. Reaction rate depends on particle size, mixing, temperature, acid concentration and available surface area. In aqueous treatment, adequate dispersion is important because undispersed solids can reduce contact efficiency and create uneven local pH conditions.
Compared with magnesium oxide, Magnesium Hydroxide is already in hydrated hydroxide form and is often selected when direct hydroxide chemistry is desired. Magnesium oxide reacts with water to form magnesium hydroxide, but its hydration rate and reactivity vary with thermal history and surface properties. The two compounds should not be treated as interchangeable without process testing, because dosing calculations, wetting behaviour, reaction kinetics and resulting solids can differ in a working system.
Magnesium Hydroxide in wastewater neutralization
In wastewater treatment, Magnesium Hydroxide can neutralize acidic process streams by consuming available acidity and forming magnesium-containing salts. Its limited solubility may help moderate the release of alkalinity, which can be advantageous where controlled pH movement is desired. Actual treatment performance depends on wastewater composition, buffering capacity, mixing, residence time, temperature and the target discharge conditions. Jar testing or equivalent process evaluation is appropriate before full-scale adoption.
Magnesium Hydroxide differs from sodium hydroxide and calcium hydroxide in both solubility and cation chemistry. Sodium hydroxide dissolves rapidly and can create sharp local pH increases, while calcium hydroxide supplies calcium and may form characteristic precipitates. Magnesium Hydroxide generally offers lower immediate solubility, so feed preparation, agitation and solids management require separate evaluation. The best choice depends on neutralization rate, downstream chemistry, sludge behaviour and permitted operating limits.
Magnesium Hydroxide for polymers and flame retardancy
Magnesium Hydroxide is used as a mineral flame-retardant component in selected polymer systems. During heating, it can decompose endothermically to magnesium oxide and water, allowing the released water vapour and heat absorption to contribute to fire-response behaviour. Its effectiveness depends strongly on loading, particle size, surface treatment, polymer type, dispersion and the complete additive package. A particular Magnesium Hydroxide material should therefore be assessed in the finished compound rather than assumed suitable from chemical identity alone.
Aluminium hydroxide is a closely related mineral flame-retardant comparison, but its decomposition temperature and thermal profile differ from Magnesium Hydroxide. That distinction can affect processing windows and the temperature at which each material contributes to heat absorption and water release. Magnesium Hydroxide may be preferred for some higher-temperature polymer processes, yet increased mineral loading can influence viscosity, mechanical properties, surface appearance and density. Compound-specific testing remains essential for balanced performance.
Magnesium Hydroxide formulation and analytical considerations
In pharmaceutical and personal-care development, Magnesium Hydroxide may be incorporated as an alkaline active or functional ingredient, including in antacid formulations. Formulators commonly examine particle-size distribution, sedimentation, wetting, suspension stability, acid-neutralizing behaviour and compatibility with excipients. The name alone does not establish suitability for ingestion or topical use. Finished-product requirements, applicable monographs, local regulations and intended route of administration must determine whether a selected material can be considered.
Analytical work on Magnesium Hydroxide can distinguish identity from practical performance. Identification may involve elemental, spectroscopic or diffraction techniques, while neutralization testing examines reaction with a defined acid under controlled conditions. Moisture, carbonate formation, insoluble matter and particle behaviour may affect formulation results without changing the basic formula H2MgO2. Results should be interpreted against the intended application and its acceptance criteria rather than relying on a single analytical measurement.
Frequently asked questions
Questions about Magnesium Hydroxide
What is the chemical formula of Magnesium Hydroxide?
Magnesium Hydroxide has the molecular formula H2MgO2, commonly written as Mg(OH)2 to show its hydroxide structure. The formula indicates one magnesium center associated with two hydroxide groups. This composition explains why the compound behaves as an inorganic base and why it can react with acids to form magnesium salts and water. The formula should not be confused with magnesium oxide, which is MgO and represents a different compound with different hydration and reaction behaviour. Although Magnesium Hydroxide may decompose to magnesium oxide and water when heated sufficiently, that transformation does not mean the two materials are identical during ordinary formulation or treatment operations.
How does Magnesium Hydroxide neutralize acid?
Magnesium Hydroxide neutralizes acid through reaction of its hydroxide component with hydrogen ions. In simplified form, the hydroxide and hydrogen ions combine to produce water, while magnesium associates with the acid’s anion to form a magnesium salt. Because Magnesium Hydroxide is sparingly soluble, the reaction can be slower and more surface-dependent than with a highly soluble base such as sodium hydroxide. Mixing, particle size, temperature, acid strength and buffering substances all influence the observed rate. A process may therefore require adequate agitation and residence time to achieve uniform neutralization. Actual dosing should be established from the specific acid stream and operating target.
Why is Magnesium Hydroxide used in some flame-retardant polymer systems?
When heated, Magnesium Hydroxide can decompose into magnesium oxide and water. This transformation absorbs heat and releases water vapour, mechanisms that may help reduce heat build-up and dilute combustible gases in some polymer systems. The resulting magnesium oxide can also contribute to a mineral residue. Performance is not determined by chemistry alone: polymer type, additive loading, particle size, surface treatment, dispersion and processing temperature are important. Higher loading may affect viscosity, strength, appearance and density. Aluminium hydroxide is a related alternative with a different decomposition profile, so compound developers generally compare both materials under the actual processing and fire-test conditions.
How does Magnesium Hydroxide differ from magnesium oxide?
Magnesium Hydroxide, Mg(OH)2, contains hydroxide groups and is a hydrated inorganic base. Magnesium oxide, MgO, contains oxygen without hydroxide and can react with water to form Magnesium Hydroxide. Their practical behaviour differs because magnesium oxide reactivity depends strongly on calcination history, surface area and hydration kinetics. Magnesium Hydroxide is often selected when a sparingly soluble hydroxide is wanted directly, while magnesium oxide may be chosen for different thermal, refractory or reactive properties. They can also differ in bulk handling, dispersion, neutralization rate and decomposition behaviour. Substitution should therefore be supported by application-specific calculations and testing rather than formula-based assumption.
Can Magnesium Hydroxide be used in wastewater treatment?
Magnesium Hydroxide can be used in selected wastewater-treatment processes to neutralize acidic streams and adjust pH. Its sparingly soluble nature may provide a more gradual alkaline response than highly soluble bases, potentially helping operators manage local pH spikes when the system is properly mixed. Suitability depends on acidity, buffering capacity, flow variation, temperature, residence time, solids separation and discharge requirements. Magnesium-containing reaction products may also influence downstream treatment or sludge characteristics. Pilot or laboratory evaluation is prudent before implementation, because performance in one wastewater cannot be assumed for another. Local environmental requirements and process controls remain part of the application assessment.
What formulation factors matter when evaluating Magnesium Hydroxide?
Important formulation factors include particle-size distribution, surface area, wetting, dispersion, sedimentation, moisture, carbonate formation and compatibility with other ingredients. In a liquid suspension, poor wetting or inadequate agitation can produce settling and uneven dosing. In polymers, particle treatment and dispersion can influence viscosity, mechanical properties and flame-retardant response. In antacid formulations, acid-neutralizing behaviour and finished-product consistency require particular attention, along with the applicable pharmaceutical requirements. Magnesium Hydroxide should be evaluated in the complete formulation because excipients, processing conditions and concentration can change its observed performance. Chemical identity alone cannot establish suitability for every product or route of use.
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